宋遼太平時期，秘密組織「鳳火軍」培養的特工唐紫煙被安插在京都皇城司任職。在她欲隱退與夫君周乾安安度此生時，夫君卻被鳳火軍抓走以脅迫，給唐紫煙下達了新任務：刺殺來訪的北朝特使皇太弟。未料，周乾安被鳳火軍射殺命喪身前，唐紫煙決心扳倒鳳火軍，佯裝不為所動繼續深入下一步刺殺計劃…
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